No.
Really, read the manual. Sure you can mess about and work a fair bit out yourself, but really, read the manual. Or at least have it close by for reference. There are a load of options in this thing, not just in terms of the amp/FX, but the internal routing, the physical I/O, the global stuff, etc. There are also a lot of parameters that you'll probably want to be looking up what they actually do, especially in the adv. parameters of various blocks.
On top of that though, understanding what stuff does can give you ideas on how to better use the thing, come up with things you otherwise might not have thought of trying, etc.
Also... as well as the manual, the Axe-FX Wiki is a great resource.